Preheat oven to 350 degrees Fahrenheit.
Place peeled and sliced potatoes, sliced leeks, and olive oil in a large mixing bowl, season with salt and pepper, then gently toss to mix well.
Transfer mixture to 6x9-inch baking dish and pat gently to form an even layer.
Cover dish with foil and bake in oven for 1 1/2 hours, or until potatoes are tender.
Let cool completely at room temperature for 1 hour, then cover with plastic wrap and chill in refrigerator for 1-2 hours.
When ready to serve, preheat oven to 450 degrees Fahrenheit.
Cut potatoes into 4 even sections then, using a metal spatula, transfer squares to a rimmed baking sheet and place in oven, baking for 30 minutes, or until the tops are browned.